เอกสารอ างอ ง CM

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1 เอกสารอ างอ ง ช ต มา ศร ว บ ลย, เคม ว เคราะห พ นฐาน, มหาว ทยาล ยรามค าแหง หมายเลขการพ มพ 47300, พ.ศ Ayres, G.H, Quantitative Chemical Analysis, 2 ed., A Haper & Row, New York, Bassett, J., R.C. Denney; G.H. Jeffery and J. Mendham, Vogel s Texbook of Quantitative Inorganic Analysis, 4 ed., The English Language Book Society and Longman, (Revised edition) Braithwait, A. and F.J. Smith, Chromatographic Method, 5 ed., Blackie Acadamic & Professional, London, Christain, G.D., Analytical Chemistry, 2 ed., John Wiley & Sons, Day, R.A. Jr. and A.L. Underwood, Quantitative Analysis, 3 ed., Prentice Hall Inc., Ewing, G.W., Instrumental Methods of Chemical Analysis, 3 ed., McGraw Hill Book Company, New York, Friz, J.S. and G.H. Schenk, Quantitative Analysis Chemistry, Boston : Allyn and Bacon, Hamiton, L.E. and S.G. Simpson, Quantitative Chemical Analysis, 12 ed., Macmillan; New York, Harvey Diehl, Quantitative Analysis, ed., Ames Iowa, Hermann, J.A. and H. Irving, Separation Methods in Analytical Chemistry, Interscience Publishers, John Wiley & Sons, New York, Kenner, C.T. and K.W. Busch, Quantitative Analysis, Macmillan, New York, Laidler, K.J., Physical Chemistry with Biological Application, Benjamin Cuummings Publish Co., Inc., CM

2 Laitinen, H.A. and Walter E. Harris, Chemical Analysis, 2 ed., McGraw Hill, Inc., Meloan, C.E. and R.W. Kiser, Problems and Experiments in Instrumental Analysis, Charles E. Merrill Publishing Co., Morison, G.H. and H. Freiser, Solvent Extraction in Analytical Chemistry, John Wiley & Sons, Inc., Nina Hadden and Fred Baumann, Basic Liquid Chromatography, Varian Aerograph, Pecsok, R.L. ; L. Donald Shields ; T. Cairns and I.G. McWilliam, Modern Methods of Chemical Analysis, 2 ed., John Wiley & Sons, Inc, Peter, G.D. ; John. Hayes and Gary M. Hieftje, Chemical Separations and Measurement, W.B. Saunders Company, Robards, K. ; P.R. Haddad and P.E. Jackson, Principles and Practice of Modern Chromatographic Methods, Academic Press, Harcourt Brace Company, London, Ramette R.W., Chemical Equilibrium and Analysis, Addison Wesley Publishing Company, Reilley, C.N. and D.T. Sawyer, Experimentals for Instrumental Methods, McGraw Hill Book Company, Inc., New York, Ringbom, A., Complexation in Analysis Chemistry, Robert E. Krieger Publishing Company, Huntington, New York, Robert D. Braun, Introduction to Chemical Analysis, McGraw Hill Book Company, New York, Robert E. Van Atta, Instrumental Methods Analysis for Laboratory Technicians, Department of Chemistry, Ball State University, Muncie, Indiana, Sawyer, D.T. ; William R. Heineman and Janice M. Beebe Chemistry Experiments for Instrumental Methods, John Wiley & Sons, New York, CM 334

3 Simpson, C.F., Techniques in Liquid Chromatrography, A Wiley Heyden Publication, John Wiley & Sons, New York, Skoog, D.A. and D.M. West, Fundameutal of Analytical Chemistry, 3 ed., Holt Rinehart and Winston, Inc., New York, Skoog, D.A. and D.M. West, Principles of Instrumental Analysis, Holt Rinehart and Winston, Inc., New York, Skoog, D.A. and D.M. West, Principles of Instrumental Analysis, 2 ed., Holt Saunders International Edition, Japan, Smith, I. And J.E. Feinberg. Paper & Thin Layer Chromatography and Electrophoresis, 2 ed., Shandon Scientific Company Ltd., Willard, H.H. ; L.L. Merritt, Jr. and J.A. Dean, Instrumental Methods of Analysis, 5 ed., D. Van Nostrand Company, New York, CM

4 344 CM 334

5 ด ชน Adjusted flow rate, 268 Counter current extraction, 69 Adjusted rentention volume, 270 Craig apparatus, 70 Adsorption chromatography, 162 Degree of cross linking 209, 221 Adsorption isotherm, 4 Descending development, 146 Analytical separations, 1 Detectors : Anion exchangers, 211 (see also specific types if detectors) Ascending development, 146 Discontinuous infusion extractor, 90 Asymmetry factor, 212 Distribution coefficient, 3, 24, 34, 99 Band width, 321 Distribution ratio, 35 Batch extraction 33 Eddy diffusion, 110, 276 Binder, 157 Efficiency : Bubble flowmeter, 288 of chromatography, 116 Capacity factor, 100ม 132 of extraction, 45 Capillary action, 140 in gas chromatography, 275 Capillary column, 291 Effluent, 249 Carrier gas, 286 Electrochromatography 198 Cation exchange resin, 209 Electron capture detector 306 Chromatogram, 109 Electrophoresis, 197 Chromatography: gel 198 theory of elution, 107 paper 198 definition of, 24 Electrostatic force, 221 efficiency of, 116 Eluate, 25, 249 plate theory, 116 Elution analysis, 25, 249 resolution in, 119 gradient, 174 theory, 99 Exclusion chromatography, 26, 193 (see also specific types of chromatography) Exclusion limit, 194 Column chromatography : 25, 162 Extraction constant 61 liquid solid chromatography, 162 Extraction of solid, 88 stationary phase, 171 Flame photometric detector, 304 technique in operation, 168 Flame-ionization detector, 300 Continuous infusion extractor, 89 Flow rate, 266 Continuous extraction, 68 Flowmeters, 267, 288 CM

6 Gas chromatography, 25, 265 Ion exchange 26, 162 apparatus for, 285 chromatography, 207 carrier gas for, 286 applications of 256 columns, 290 column operations 249 detectors, 298 effect of complexing agent 239 efficiency in, 275 effect of ph 232 flow rate effect on, 266 Ion exchange capacity 216 flowmeters, 288 Ion exchange equilibria, 223 injection systems 289 Ion-exchange resins, 208 principle of, 265 Isocratic condition 177 qualitative analysis with, 309 Isoelectric point, 237 quantitative analysis, 318 Liquid chromatography, 26 retention time and retention 102, 266 Liquid-liquid chromatography, 26, 139 volume in Liquid- liquid extraction, 33 solid supports for, 291 Loading capacity, 217 temperature effects on, 295 Longitudinal diffusion, 110 Gas-liquid chromatography, 25 Mixbed ion exchange resin 214 Gas-solid chromatography, 25, 265 Mobile phase, 3, 25 Gaussian distribution, 78 Multistage process, 1 Gel-electrophoresis, 197 Non equilibrium mass transfer, 110 Gel filtration chromatography, 194 Net retention volume, 270 Gradient elution analysis, 174 Optimum velocity, 278 High-performance liquid 25, 176 Packed column, 290 Height equivalent of a 116 Paper chromatography : 26, 140, 143 theoretical plate, (HETP), ascending, 146 liquid solid chromatography, 26, 139 descending, 146 Hydrogen flame detector, 299 detection, 148 Influent, 249 developing, 145 Integrator method, 322 spot location with, 144 Ion chromatography, 252 two-dimensional, 146 Paper electrophoresis, 198 Partition chromatography, 162 Partition coefficient, 3, CM 334

7 ph : Solvent front, 142 effect on ion-exchange 232 Soxhlet extractor, 89 chromatography, Specific retention volume, 266 Plane chromatography, 26, 139 Station phase, 2, 25 Planimeter, 322 Stationary liquid phase, 293 Plate height (see also Height 163 Stationary solid phase 291 equivalent of a theoretical plate) Stripping column, 253 Plate theory 111 Temperature effects in gas 296 Precolumn 176 chromatography, Reflux ratio, 21 Temperature programming, 296 Relative retention, 104 Theoretical plate, 111 Resolution in chromatography, Thermal conductivity detectors, 302 Retardation factor, 140 Thin layer chromatography, 26, 140, Retention index, Retention ratio 103 preparation of separating layer, 157 Retention time, 102 sample application 158 Retention volume, 103 detection 162 Reverse-phase chromatography, 144, 172 developing 158 Sampling valve 180 Two-dimension development, 146 Selectivity coefficient, 224 Van deemter equation, 173, 169 Separating column, 253 Void volume 196 Separation factor, 64, 226 Void fraction, 231 Separation methods in chemical analysis 1 Volume distribution coefficient, 231 by chromatography, 24 Zwitterions ion 237 by electrodeposition, 20 by precipitation, 7 by solvent extraction 23 Sephadex, 194 Single stage process, 1 Solid-liquid extraction, 88 Solid support, 172 Solvent extraction, 23, 33 CM

8 348 CM 334